Silver(I) 2,2'-(1,2-Phenylenedisulfanediyl)diacetic Acid as a Molecular Building Block for a Silver(I)-Cadmium(II) Coordination Polymer.

نویسندگان

  • Ioana Georgeta Grosu
  • Christiane Berghof
  • Peter Lönnecke
  • Luminita Silaghi-Dumitrescu
  • Evamarie Hey-Hawkins
چکیده

Starting from heterotopic multidentate ligand 2,2'-(1,2-phenylenedisulfanediyl)diacetic acid, (RS,RS,RS,RS/SS,SS,SS,SS)-[Ag{1,2-C6H4(SCH2COOH)2-κ2S,S'}2]BF4 (1) was prepared and further used as a building block for the synthesis of heterobimetallic Ag-Cd coordination polymer [Ag2Cd2{1,2-(OOCCH2S)2C6H4}3 (H2O)3·5H2O]n (2). Both complexes were characterized by X-ray structure analysis and conventional spectroscopic techniques.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Poly[bis(μ3-thio­cyanato-κ3 N:S:S′)(μ2-thio­cyanato-κ2 N:S)(4′-p-tolyl-2,2′:6′,2′′-terpyridine-κ3 N,N′,N′′)cadmium(II)silver(I)]

The title compound, [AgCd(NCS)(3)(C(22)H(17)N(3))](n), is a hetero-atom ribbon coordination polymer. The central Cd atom is chelated by the 4'-p-tolyl-2,2':6',2''-terpyridine ligand and is coordinated by the N atoms of three thio-cyanate ions in an octa-hedral geometry whereas the Ag atom is coordinated by the four S atoms of four thio-cyanate ions in a distorted tetra-hedral geometry. Of the t...

متن کامل

Chitosan/nanosilver Nanofiber Composites with Enhanced Morphology and Microbiological Properties

In recent years natural polymers have been widely used in biomedical applications. Application of natural and biocompatible polymers in wound dressing, medical sutures and tissue engineering are extensively growing. Additional properties are provided when metal nanoparticles such as silver and gold are incorporated in to the fibers. However, nowadays nanofibers due to their inherent properties ...

متن کامل

Evaluation of antioxidant, anti-cancer and anti-inflammatory characteristics of bio-synthesized silver nanoparticles produced by waste extract of Rheum ribes L.

Background: This study was designed to evaluate the antioxidant, anti-inflammation and anti-cancer potency of silver nanoparticles produced by waste Rheum ribes L. extract. Materials and Methods: in this study, 10 gr of dried Rheum ribes L powder after 3 hours dissolving at 37°C was filtered and applied for silver nanoparticles preparation. Particle size, X-ray diffractometer (XRD), Fourier tra...

متن کامل

The hydrothermal synthesis and X-ray crystal structure of Ag (1)-4, 4"-bipyridine-based coordination polymer

Hydrothermal synthetic were studied for the preparation of coordination polymeric material basedon Ag (I) and 4, 4"-bipy. A polymeric compound [Ag (4, 4'-bipy)].NO3. (I), was prepared andstructurally characterized by single crystal X-ray diffraction. Compound 1(91% yield) was isolatedfrom the reaction of AgNO3 with 4, 41bipy in 2:1 molar ratio. In compound I. each silver (I) islinked to two nit...

متن کامل

Metalation studies of 3- and 4-pyridyloxycyclophosphazenes: metallamacrocycles to coordination polymers.

Pyridyloxy cyclophosphazenes, spiro-N3P3(O2C12H8)(O-C5H4N-3)4 (L1), dispiro-N3P3(O2C12H8)2(O-C5H4N-3)2 (L2) and dispiro-N3P3(O2C12H8)2(O-C5H4N-4)2 (L3) were prepared and characterized. The crystal structure of L1 was determined which showed that the cyclophosphazene ring is planar. The reaction of L1 with anhydrous copper(II) chloride or silver nitrate afforded L2M4 metallamacrocycles [{L1}2{Cl...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:
  • Molecules

دوره 20 5  شماره 

صفحات  -

تاریخ انتشار 2015